First check if your command line recognizes mysql command. If not go to command & type in:
set path=c:\wamp\bin\mysql\mysql5.1.36\bin
Then use this command to export your database:
mysqldump -u YourUser -p YourDatabaseName > wantedsqlfile.sql
You will then be prompted for the database password.
This exports the database to the path you are currently in, while executing this command